4-(4-Nitrobenzyl)morpholine
نویسندگان
چکیده
In the title compound, C(11)H(14)N(2)O(3), an inter-molecular inter-action between a nitro group O atom and a neighboring benzene ring helps to stabilize the crystal structure [N⋯centroid = 3.933 (2) Å]. No classical hydrogen bonds are observed in the crystal packing.
منابع مشابه
4-{[1-(4-Ethoxyphenyl)-5-methyl-1H-1,2,3-triazol-4-yl]diphenylmethyl}morpholine
The title compound, C(28)H(30)N(4)O(2), synthesized from 4-[1-(4-ethoxy-phen-yl)-5-methyl-1H-1,2,3-triazol-4-yl]diphenyl-meth-an-ol and morpholine, consists of a subsituted triazolyl group and a morpholinyl group that crowd the aliphatic C atom of a diphenyl-methyl unit [C(triaz)-C-N(morph) = 110.1 (1)° and C(phen-yl)-C-C(phen-yl) = 103.9 (1)°]. The morpholine ring adopts a chair conformation.
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In the ionic title compound, K(+)·C(5)H(8)NOS(2) (-)·H(2)O, the morpholine ring of the morpholine-4-carbodithio-ate anion has a chair conformation. The potassium cation is coordinated by four S and four O atoms in a bipyramidal reversed geometry. In the crystal, the three components are linked, generating infinite two-dimensional networks that lie parallel to the bc plane. These layers are link...
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In the title compound, C(15)H(18)N(4)O(7), the morpholine rings adopt chair conformations. The benzene ring forms dihedral angles of 55.94 (7) and 63.19 (7)° with the planes through the C atoms of the two morpholine rings.
متن کاملN-[4-(Morpholinodiazenyl)phenyl]acetamide
The title compound, C(12)H(16)N(4)O(2), is a member of a family of morpholine-substituted aromatic diazenes. Conjugation of the diazene group π-system and the lone pair of electrons of the morpholine N atom is evidenced by a lengthened N=N double bond of 1.2707 (19) Å and a shortened N-N single bond of 1.346 (2) Å. The bond angles at the morpholine N atom range from 113.52 (14) to 121.12 (14)°,...
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The reaction of N-[4-(chloroacetyl)aminobenzenesulphonyl]morpholine (IV) in acetone or dimethyl-formamide with amine derivatives, 4-aminotriazoles (I,II) or sulpha drugs yielded the corresponding N-[4-(substituted glycyl)aminobenzenesulphonyl]-morpholine derivatives (V-XV). Moreover, some derivatives of N-[4-(alkoxyacetyl)aminobenzenesulphonyl]morpholine (XVI-XXI) were synthesized. The reaction...
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